I really didn't like this series at all. I thought the action was pathetic and Spider-Man was made out to look way too weak. Unlike X-Men that took major storylines like the Phoenix and Dark Phoenix saga and did decent to pretty good jobs bringing them to animation, I don't think Spiderman did any of its storylines well.
I barely remember watching this on TV back in the mid 90's, but all I remember was being bored and irritated. Certainly something I won't be re-watching. I'll be looking at the best Spidey comics if I want to get into Spider Man.
(from Wikipedia) The series tells the story of a 19-year-old Peter Parker in his first year at Empire State University, and his alter-ego Spider-Man. As the story begins, Peter has already gained his powers, is single and a part-time photographer for the Daily Bugle. The show features most of Spider-Man's classic villains, including the Kingpin, the Green Goblin, the Lizard, the Scorpion, Doctor Octopus, Mysterio, the Rhino, the Shocker, The Vulture, and the Chameleon, as well as more recent villains such as Venom, Carnage, and the Hobgoblin. Over the course of the series the single Peter Parker contends with the romantic interests of Mary Jane Watson, Felicia Hardy and her alter ego, the Black Cat.