Not even sure how to this James Bond-esque style, but it's one of Supreme Beings' best songs. If you've never met SBL, they're from Los Angeles where almost everything good comes from (except bacon from Denmark). http://www.youtube.com/watch?v=ic7_Dl3lGoA
If you liked Amelie and the music, you'll enjoy this. I like most of Tiersen's work - weird, energetic and dramatic all the same time - and this song captures it all... http://www.youtube.com/watch?v=qBZPa-kLLCE
Trust David Fincher films to have a solid soundtrack - Fight Club's is one of the most original and identifiable I can think of. The Dust Brothers captured the soul of the movie perfectly in this frenetic opening piece (http://www.youtube.com/watch?v=-D1vwKi0FTA&feature=related). This was possibly the only time I've ever seen a film and within 90 seconds just knew it was going to be spectacular.